EXTRACTION OF PERCHLORIC-ACID BY THE NITROBENZENE SOLUTION OF P-NONYLPHENYLNONAETHYLENE GLYCOL

Authors
VANURA P JEDINAKOVAKRIZOVA V IVANOVA P
Citation
P. Vanura et al., EXTRACTION OF PERCHLORIC-ACID BY THE NITROBENZENE SOLUTION OF P-NONYLPHENYLNONAETHYLENE GLYCOL, Journal of radioanalytical and nuclear chemistry, 208(1), 1996, pp. 271-281
Citations number
11
Categorie Soggetti
Chemistry Analytical","Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
208
Issue
1
Year of publication
1996
Pages
271 - 281
Database
ISI
SICI code
0236-5731(1996)208:1<271:EOPBTN>2.0.ZU;2-T
Abstract
Extraction of perchloric acid by the nitrobenzene solution of Slovafol 909 (p-nonylphenylnonaethylene glycol, L) has been investigated and t he composition of species in the organic phase has been determined. It has been found, that perchloric acid is full dissociated in both phas e, and H+ ion in the organic phase is partially solvated by one or two molecules of p-nonylphenylnonaethylene glycol. Extraction and stabili ty constants of HL+ and HL2+ species in the organic phase has been eva luated.