Entanglement of protons in organic molecules: An attosecond neutron scattering study of C-H bond breaking

Citation
Ca. Chatzidimitriou-dreismann et al., Entanglement of protons in organic molecules: An attosecond neutron scattering study of C-H bond breaking, J AM CHEM S, 123(48), 2001, pp. 11945-11951
Citations number
37
Categorie Soggetti
Chemistry & Analysis",Chemistry
Journal title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN journal
00027863 → ACNP
Volume
123
Issue
48
Year of publication
2001
Pages
11945 - 11951
Database
ISI
SICI code
0002-7863(200112)123:48<11945:EOPIOM>2.0.ZU;2-9
Abstract
Interactions between adjacent particles of condensed phases can lead to qua ntum correlation phenomena. like quantum interference, entanglement, deloca lization, and "Schrodinger's cat" states. Such correlations are theoretical ly expected to be extremely short-lived because of environmental disturbanc es. Here, we present experimental evidence for quantum entanglement between well localized protons of C-H bonds of 2-isobutoxyethanol dissolved in D2O . The applied experimental method is neutron Compton scattering (NCS), whic h has a characteristic time window in the subfemtosecond time range. Our NC S results reveal that, in the subfemtosecond time scale, the measured cross -section density, and thus, in simple terms, the effectively present concen tration, of the H atoms is "anomalously" reduced by similar to 20%. Affecti ng the microdynamics of protons of covalent C-H bonds, this novel effect ma y have a broad range of chemical and biological applications.