Reactivity of [SnPh3(eta(1)-2-PyS)] towards Pt and Ni complexes

Authors
de Castro, VD Filgueiras, CAL de Lima, GM Gambardella, MTP Speziali, NL
Citation
Vd. De Castro et al., Reactivity of [SnPh3(eta(1)-2-PyS)] towards Pt and Ni complexes, MAIN GR MET, 24(11), 2001, pp. 761-764
Citations number
18
Categorie Soggetti
Chemistry
Journal title
MAIN GROUP METAL CHEMISTRY
ISSN journal
07921241 → ACNP
Volume
24
Issue
11
Year of publication
2001
Pages
761 - 764
Database
ISI
SICI code
0792-1241(2001)24:11<761:RO[TPA>2.0.ZU;2-9
Abstract
The reaction of [SnPh3(eta (1)-2-PyS)] (1) with both [cis-Pt(PPh3)(2)Cl-2] and [Pt(PPh3)(2)(C2H4)] yielded the same platinum derivative, [trans-Pt(PPh 3)(2)(eta (1)-2-PyS)(2)] (2). The tin-containing products were identified a s SnPh3Cl and Sn2Ph6 for the first and second reactions, respectively. The same experiment with [cis-Ni(PPh3)(2)Cl-2] led to the formation of an insol uble product Ni(2-PyS)(2) and of [SnPh3(OPPh3)Cl] (3). Compounds (1), (2) a nd (3) were studied by i.r., NMR spectroscopies and their X-ray structures were revised.