N-cyclopropylimine-1-pyrroline rearrangement. A novel photochemical reaction

Authors
Campos, PJ Soldevilla, A Sampedro, D Rodriguez, MA
Citation
Pj. Campos et al., N-cyclopropylimine-1-pyrroline rearrangement. A novel photochemical reaction, ORG LETT, 3(25), 2001, pp. 4087-4089
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
25
Year of publication
2001
Pages
4087 - 4089
Database
ISI
SICI code
1523-7060(200112)3:25<4087:NRANPR>2.0.ZU;2-4
Abstract
[GRAPHICS] A novel aza-(vinylcyclopropane-cyclopentene) photochemical rearrangement is reported. 1-Pyrrolines are easily synthesized in good yields from N-cyclop ropylimines. Hydrogen, alkyl, and aryl groups can be placed anywhere within the system, and the reaction proceeds regiospecifically.