Efficient enantioselective hydrosilylation of ketones catalyzed by air stable copper fluoride-phosphine complexes

Authors
Sirol, S Courmarcel, J Mostefai, N Riant, O
Citation
S. Sirol et al., Efficient enantioselective hydrosilylation of ketones catalyzed by air stable copper fluoride-phosphine complexes, ORG LETT, 3(25), 2001, pp. 4111-4113
Citations number
25
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
25
Year of publication
2001
Pages
4111 - 4113
Database
ISI
SICI code
1523-7060(200112)3:25<4111:EEHOKC>2.0.ZU;2-7
Abstract
[GRAPHICS] Copper(II) fluoride-chiral diphosphine systems catalyze the hydrosilylation of several ketones with moderate to excellent enantioselectivities. An oxy gen acceleration effect was observed and led to a practical protocol with l ow catalyst loading.