Excess enthalpy data in some binary systems containing non electrolyte solution and their correlations at 298.15 K

Citation
H. Iloukhani et al., Excess enthalpy data in some binary systems containing non electrolyte solution and their correlations at 298.15 K, PHYS CHEM L, 39(5), 2001, pp. 565-580
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICS AND CHEMISTRY OF LIQUIDS
ISSN journal
00319104 → ACNP
Volume
39
Issue
5
Year of publication
2001
Pages
565 - 580
Database
ISI
SICI code
0031-9104(2001)39:5<565:EEDISB>2.0.ZU;2-9
Abstract
Excess enthalpy data measured at 298.15 K were collected from the literatur e. The data contains 48 binary systems (812 data points). The experimental data were correlated by Redlich-Kister equation. In this work the following thermodynamics models were also tested. Wilson, NRTL models: and their par ameters were calculated. A modified NRTL with a composition-dependent (alph a (12)) parameter was also proposed. The correlation of excess enthalpy dat a in the systems using this model provides good results.