A. Cao et al., Studies on syntheses and physical characterization of biodegradable aliphatic poly(butylene succinate-co-epsilon-caprolactone)s, POLYMER, 43(3), 2002, pp. 671-679
Biodegradable aliphatic poly(butylene succinate-co-epsilon -caprolactone) (
PBSCs) were synthesized through a polycondensation with titanium tetraisopr
oxide (TTP), diphenylphosphinic acid (DPPA) and stannous octoate (Sn(Oct)(2
)) as the novel co-catalysts. By means of gel permeation chromatography (GP
C) and nuclear magnetic resonance spectrometer (NMR), it was revealed that
the PBSC copolyesters had number average molecular weights Al higher than 5
.0 x 10(4), and that the polycondensations were in well agreement with a ra
ndom copolymerization model. With respect to thermal properties, melting po
int, heat of fusion and glass transition temperature were found to decrease
with increasing the CL/BS unit molar ratio up to 0.92, while thermal stabi
lity monotonously decreased with increasing the CL unit population spanning
the whole CL unit composition. X-ray diffraction patterns indicated that t
he BS-rich/CL-rich PBSC organized the corresponding PBS/PCL-type of crystal
structure. Moreover, it is worth to note that the PBS copolymerized with a
n appropriate amount of the minor CL component could significantly increase
the fracture elongation of the resultant PBSC, and that mechanical propert
ies of PBSC strongly depended on its CL unit population. In addition, biode
gradabilities of PBSCs as well as PBS and PCL were tentatively assessed in
a kind of compost soil, and the results suggest that chain flexibility may
play an important role in the biodegradation as another factor besides the
specificity of unit chemical structure and morphology. (C) 2001 Elsevier Sc
ience Ltd. All rights reserved.