M. Misheva et al., Gamma irradiation effect upon positron annihilation in ultra high molecular weight poly(ethylene oxide), RADIAT PH C, 62(5-6), 2001, pp. 379-385
Positron annihilation technique was used to reveal the evolution of small p
ore structure of semi-crystalline ultra high molecular weight poly(ethylene
oxide) under gamma -irradiation. It has been established that the structur
e of poly(ethylene oxide) is improved under low dose irradiation (< 20 kGy)
, while the concentration of free-volume holes in amorphous regions increas
es at higher doses. The results were compared with those from small angle X
-ray scattering and wide angle X-ray scattering measurements of the same sa
mples. (C) 2001 Elsevier Science Ltd. All rights reserved.