DIORGANOTIN(IV) DICHLORIDE COMPLEXES OF SOME N-ARYLFURFURALNITRONES

Authors
ALALLAF TAK ABDULRAHMAN A
Citation
Tak. Alallaf et A. Abdulrahman, DIORGANOTIN(IV) DICHLORIDE COMPLEXES OF SOME N-ARYLFURFURALNITRONES, Synthesis and reactivity in inorganic and metal-organic chemistry, 27(7), 1997, pp. 985-996
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
27
Issue
7
Year of publication
1997
Pages
985 - 996
Database
ISI
SICI code
0094-5714(1997)27:7<985:DDCOSN>2.0.ZU;2-#
Abstract
Some new diorganotin(IV) dichloride complexes of the general formula R 2SnCl2.L, where R = Me, Bu, Ph; L = OCH = CHCH = C- CH = N(O)C6H4X (X = H, p - CH3, CH3O, CH3CO, F, Cl or Br) have been prepared and charact erized by elemental analyses, and IR, H-1 and C-13 NMR spectroscopy. T he spectral data show that the nitrone ligands coordinate with tin thr ough the most active oxygen atom of the N-oxide to give penta-coordina te tin complexes. An explanation for such observations is given.