SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW N-ALKYLATED AZACROWN LIGAND AND ITS COPPER(II) COMPLEX

Authors
XU XY MA WX WANG ZL LUO QH NI SS ZHOU XG ZHOU ZY
Citation
Xy. Xu et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW N-ALKYLATED AZACROWN LIGAND AND ITS COPPER(II) COMPLEX, Synthesis and reactivity in inorganic and metal-organic chemistry, 27(7), 1997, pp. 1059-1069
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
27
Issue
7
Year of publication
1997
Pages
1059 - 1069
Database
ISI
SICI code
0094-5714(1997)27:7<1059:SACOAN>2.0.ZU;2-P
Abstract
A new pendant-arm macrocyclic ligand, N,N'-bis(2-cyanoethyl)-3,4:9, 10 -dibenzol, 12-diaza-5, 8-dioxacyclopentadecane (L), was synthesized in 93% yield by alkylating :9,10-dibenzo-1,12-diaza-5,8-dioxacyclopentad ecane with acrylonitrile. Its crystal structure was determined and its copper(II) complex was also prepared. All compounds were characterize d by IR, NMR, elemental analyses and UV-Vis. The complex has the formu la of CuLCl2 . 2H(2)O.