Enantio- and diastereoselective reductive aldol reactions with iridium-pybox catalysts

Authors
Zhao, CX Duffey, MO Taylor, SJ Morken, JP
Citation
Cx. Zhao et al., Enantio- and diastereoselective reductive aldol reactions with iridium-pybox catalysts, ORG LETT, 3(12), 2001, pp. 1829-1831
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
12
Year of publication
2001
Pages
1829 - 1831
Database
ISI
SICI code
1523-7060(20010614)3:12<1829:EADRAR>2.0.ZU;2-9
Abstract
[GRAPHICS] A catalytic amount of [(cod)IrCl](2) and indane-pybox converts diethylmethy lsilane, methyl acrylate, and certain aldehydes to the derived reductive al dol adduct with good enantio and diastereocontrol.