Polymerization of ethylene by the electrophilic heteroscorpionate-containing complexes [TiCl3(bdmpza)] and [TiCl2(bdmpza){O(CH2)(4)Cl}] (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate)

Authors
Otero, A Fernandez-Baeza, J Antinolo, A Carrillo-Hermosilla, F Tejeda, J Diez-Barra, E Lara-Sanchez, A Sanchez-Barba, L Lopez-Solera, I Ribeiro, MR Campos, JM
Citation
A. Otero et al., Polymerization of ethylene by the electrophilic heteroscorpionate-containing complexes [TiCl3(bdmpza)] and [TiCl2(bdmpza){O(CH2)(4)Cl}] (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate), ORGANOMETAL, 20(12), 2001, pp. 2428-2430
Citations number
39
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
12
Year of publication
2001
Pages
2428 - 2430
Database
ISI
SICI code
0276-7333(20010611)20:12<2428:POEBTE>2.0.ZU;2-D
Abstract
Novel heteroscorpionate-containing titanium complexes, TiCl3(bdmpza) and Ti Cl2(bdmpza){O(CH2)(4)-Cl} (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate), have been prepared. Toluene solutions of these complexes with methylalumino xane catalyze the polymerization of ethylene and show a high catalytic acti vity.