Iminoacylberyllium compounds derived from octamethyl- and decamethylberyllocene and 2,6-dimethylphenyl isocyanide. Evidence for the existence of eta(5)/eta(1) isomers of beryllocenes

Authors
Conejo, MD Fernandez, R Carmona, E Gutierrez-Puebla, E Monge, A
Citation
Md. Conejo et al., Iminoacylberyllium compounds derived from octamethyl- and decamethylberyllocene and 2,6-dimethylphenyl isocyanide. Evidence for the existence of eta(5)/eta(1) isomers of beryllocenes, ORGANOMETAL, 20(12), 2001, pp. 2434-2436
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
12
Year of publication
2001
Pages
2434 - 2436
Database
ISI
SICI code
0276-7333(20010611)20:12<2434:ICDFOA>2.0.ZU;2-Q
Abstract
The existence in solution of eta (5)/eta (1) isomers of the beryllocenes Be (C5Me5)(2) and Be(C5Me4H)(2) is inferred from the results of their reaction with CNXyl to give iminoacyl products. The process is reversible and invol ves coupling of a Be-eta (1)-Cp ' group with the isocyanide.