Synthesis and characterization of organoaluminum complexes containing bi- or tridentate-substituted pyrrole ligands

Authors
Huang, JH Chen, HJ Chang, JC Zhou, CC Lee, GH Peng, SM
Citation
Jh. Huang et al., Synthesis and characterization of organoaluminum complexes containing bi- or tridentate-substituted pyrrole ligands, ORGANOMETAL, 20(12), 2001, pp. 2647-2650
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
12
Year of publication
2001
Pages
2647 - 2650
Database
ISI
SICI code
0276-7333(20010611)20:12<2647:SACOOC>2.0.ZU;2-J
Abstract
Reactions of AlCl3 with 1 equiv of Li{C4H2N(CH2NMe2)(2)-2,5} or 2 equiv of Li{C4H3N(CH2NMe2)-2} in diethyl ether at -78 degreesC afforded AlCl2{C4H2N( CH2NMe2)(2)-2,5} (1) and AlCl{C4H3N(CH2NMe2)-2} (2), respectively. Alkylati on of 1 with MeLi in diethyl ether generates the aluminum dimethyl complex 3. Compound 2 is thermally unstable and was converted to uncharacterized pr oduct in CHCl3 within 2 days at 80 degreesC. Compounds 1, 2, and 3 were cha racterized by NMR spectroscopy and X-ray structure determination.