Explicit algebraic scalar-flux models that are valid for three-dimensi
onal turbulent flows are derived from a hierarchy of second-order mome
nt closures. The mathematical procedure is based on the Cayley-Hamilto
n theorem and is an extension of the scheme developed by Taulbee. Seve
ral closures for the pressure-scalar gradient correlations are conside
red and explicit algebraic relations are provided for the velocity-sca
lar correlations in both nonreacting and reacting flows. In the latter
, the role of the Damkohler number is exhibited in isothermal turbulen
t flows with nonpremixed reactants. The relationship between these clo
sures and traditional models based on the linear gradient-diffusion ap
proximation is theoretically established. The results of model predict
ions are assessed by comparison with available laboratory data in turb
ulent jet flows.