New polyconjugated oligomers-oligoaminophenols-have been prepared by t
he oxidative polycondensation reaction of aminophenols (APs) in the pr
esence of oxidants (H2O2, NaOCl, KOH plus O-2). It has been establishe
d that the reactivity of AP increases with the series of m- < o- < p-i
somers in this reaction. The oligoaminophenols synthesized show a high
reactivity in electron-exchange processes and in reactions with the o
xirane ring of epichlorohydrin and epoxy resins. They are highly effic
ient antioxidants and antistatic agents.