Novel inorganic polymeric compounds based on the Re-4 chalcocyanide cluster complexes: synthesis and crystal structures of Mn-2[Re4Se4(CN)(12)]centerdot 6H(2)O, Cd-2[Re4Te4(CN)(12)]center dot 6H(2)O, Cu-2[Re4Te4(CN)(12)]center dot 4H(2)O and K4Re4Se4(CN)(12)center dot 6H(2)O

Authors
Mironov, YV Virovets, AV Sheldrick, WS Fedorov, VE
Citation
Yv. Mironov et al., Novel inorganic polymeric compounds based on the Re-4 chalcocyanide cluster complexes: synthesis and crystal structures of Mn-2[Re4Se4(CN)(12)]centerdot 6H(2)O, Cd-2[Re4Te4(CN)(12)]center dot 6H(2)O, Cu-2[Re4Te4(CN)(12)]center dot 4H(2)O and K4Re4Se4(CN)(12)center dot 6H(2)O, POLYHEDRON, 20(9-10), 2001, pp. 969-974
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
20
Issue
9-10
Year of publication
2001
Pages
969 - 974
Database
ISI
SICI code
0277-5387(20010430)20:9-10<969:NIPCBO>2.0.ZU;2-H
Abstract
Three new tetrahedral rhenium chalcocyanide cluster compounds, Mn-2[Re4Se4( CN)(12)]. 6H(2)O (1), Cd-2[Re4Te4(CN)(12)]. 6H(2)O (2) and Cu-2[Re4Te4(CN)( 12)]. 4H(2)O (3), exhibiting polymeric structures have been synthesized by the treatment of molecular ionic cluster compounds K(4)Re(4)Q(4)(CN)(12) (Q = Se, Te) with aqueous solutions of Mn(NO3)(2), CdSO4 and CuCl2 in gel. Th e previously unknown starting compound K4Re4Se4(CN)(12). 6H(2)O (4) was obt ained by the reaction of Re4Se4(TeCl2)(4)Cl-8 with KCN in water. All four c ompounds have been characterized by single-crystal X-ray diffraction. (C) 2 001 Elsevier Science Ltd. All rights reserved.