Sprayed CuInS2 thin films for solar cells: The effect of solution composition and post-deposition treatments

CuInS2 thin films were prepared by spray pyrolysis from solutions with diff erent compositions. Etching in KCN solution and thermal treatments in vacuu m and hydrogen were applied to as-deposited films. KCN etching removes cond uctive copper sulfide from the surface of Cu-rich films but has no effect o n matrix composition. Vacuum annealing at 500 degreesC and hydrogen treatme nt at 400-500 degreesC purifies the films, prepared from the solutions with the Cu/In = 1, from secondary phases, reduces chlorine content and improve s crystallinity. Vacuum annealing; results in n-type films due to the forma tion of In2O3 phase. Treatment in hydrogen reduces oxygen-containing residu es and results in p-type CuInS2 films with resistivity close to 10 Ohm cm. (C) 2001 Elsevier Science B.V. All nights reserved.