Novel stereocontrolled alpha- and beta-glycosidations of mannopyranosyl sulfoxides using environmentally benign heterogeneous solid acids

Authors
Nagai, H Kawahara, K Matsumura, S Toshima, K
Citation
H. Nagai et al., Novel stereocontrolled alpha- and beta-glycosidations of mannopyranosyl sulfoxides using environmentally benign heterogeneous solid acids, TETRAHEDR L, 42(25), 2001, pp. 4159-4162
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
25
Year of publication
2001
Pages
4159 - 4162
Database
ISI
SICI code
0040-4039(20010618)42:25<4159:NSAABO>2.0.ZU;2-G
Abstract
The environmentally benign and stereocontrolled glycosidations of mannopyra nosyl sulfoxides and alcohols using a heterogeneous solid acid, Nafion-H or sulfated zirconia (SO4/ZrO2) as a new activator for the direct syntheses o f both the alpha- and beta -mannopyranosides have been developed. (C) 2001 Elsevier Science Ltd. All rights reserved.