Hydroxyphenyl substituted tetrathiafulvalene vinylogues affording stable cation radical salts with unusual crystal structures

Authors
Yamashita, Y Tomura, M Imaeda, K
Citation
Y. Yamashita et al., Hydroxyphenyl substituted tetrathiafulvalene vinylogues affording stable cation radical salts with unusual crystal structures, TETRAHEDR L, 42(25), 2001, pp. 4191-4193
Citations number
13
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
25
Year of publication
2001
Pages
4191 - 4193
Database
ISI
SICI code
0040-4039(20010618)42:25<4191:HSTVAS>2.0.ZU;2-#
Abstract
TTF vinylogues containing hydroxyphenyl groups were newly prepared. They ar e stronger electron donors than BEDT-TTF and afforded their cation radical salts as single crystals upon electrochemical oxidation. X-Ray structure an alysis has revealed their unusual crystal structures, where pi -overlapping and hydrogen bonding play a crucial role in constructing them. (C) 2001 El sevier Science Ltd. All rights reserved.