Chiral bipyridine-copper(I) complex-catalyzed enantioselective allylic oxidation of cyclic alkenes

Authors
Lee, WS Kwong, HL Chan, HL Choi, WW Ng, LY
Citation
Ws. Lee et al., Chiral bipyridine-copper(I) complex-catalyzed enantioselective allylic oxidation of cyclic alkenes, TETRAHEDR-A, 12(7), 2001, pp. 1007-1013
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
12
Issue
7
Year of publication
2001
Pages
1007 - 1013
Database
ISI
SICI code
0957-4166(20010508)12:7<1007:CBCEAO>2.0.ZU;2-L
Abstract
Chiral copper(I) bipyridine complexes were prepared and used as catalysts i n thr enantioselective allylic oxidation of cyclic alkenes with tert-butyl perbenzoate. The yields ranged From moderate to good and enantioselectiviti es up to 70% were observed. (C) 2001 Elsevier Science Ltd. All rights reser ved.