State-to-state chemical reaction dynamics in polyatomic systems: Case studies

Authors
Citation
Jj. Valentini, State-to-state chemical reaction dynamics in polyatomic systems: Case studies, ANN R PH CH, 52, 2001, pp. 15-39
Citations number
115
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ANNUAL REVIEW OF PHYSICAL CHEMISTRY
ISSN journal
0066426X → ACNP
Volume
52
Year of publication
2001
Pages
15 - 39
Database
ISI
SICI code
0066-426X(2001)52:<15:SCRDIP>2.0.ZU;2-H
Abstract
This review illustrates the experimental study of chemical reaction dynamic s using methods that select the quantum states and energy of the reactants and determine the quantum states and energy of the products. The focus is r eaction dynamics in systems in which at least one of the reactants or produ cts is a polyatomic molecule. The approach taken is to select four prototyp e reaction systems as case studies to demonstrate the detail of information and insight that can come from such experiments. Thus, the review is selec tive and neither claims nor attempts to be comprehensive. Reference to and discussion of theoretical reaction dynamics are included where computationa l results directly connect with the experiments.