The optical emission properties of mass-transport regions of GaN grown by h
ydride vapor phase epitaxy are studied by cathodoluminescence imaging and s
pectroscopy. A strong donor-acceptor pair emission is observed from the mas
s-transport regions. Spatially resolved cathodoluminescence reveals a stron
g intensity contrast between the exciton and donor-acceptor bands from mass
-transport and nontransport regions. Focused Auger electron and x-ray photo
electron spectroscopies were employed to investigate the impurity incorpora
tion in the different regions. A preferential moderate increase of residual
impurity incorporation or redistribution in mass-transport regions is sugg
ested to be responsible for the observed change of the dominant radiative m
echanism. (C) 2001 American Institute of Physics.