Y. Ding et al., Why lanthanum-substituted bismuth titanate becomes fatigue free in a ferroelectric capacitor with platinum electrodes, APPL PHYS L, 78(26), 2001, pp. 4175-4177
Bi4Ti3O12, (BTO) a Bi-layered perovskite oxide, shows fatigue after repeate
d ferroelectric polarization reversals. On the other hand, Bi3.25La0.75Ti3O
12 (BLT) is fatigue free. From an extensive transmission electron microscop
y study, it was found that there is a high density of antiphase boundaries
(APBs) in BLT like in the fatigue-free SrBi2Ta2O9 but not in BTO. It is pro
posed that the existence of APBs possibly plays a key role in the fatigue-f
ree behavior of Bi-layered perovskite oxides. (C) 2001 American Institute o
f Physics.