Copper(II) complexes resulting from the oxygenation of (2,9-dimethyl-1,10-phenanthroline)copper(I) chloride in the presence of dimethylformamide

Citation
K. Oyaizu et al., Copper(II) complexes resulting from the oxygenation of (2,9-dimethyl-1,10-phenanthroline)copper(I) chloride in the presence of dimethylformamide, B CHEM S J, 74(5), 2001, pp. 869-870
Citations number
20
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
74
Issue
5
Year of publication
2001
Pages
869 - 870
Database
ISI
SICI code
0009-2673(200105)74:5<869:CCRFTO>2.0.ZU;2-T
Abstract
The oxygenation of (2,9-dimethyl-1,10-phenanthroline)copper(I) chloride in THF, followed by a treatment with DMF and acidification with HCl, afforded dichloro[2-(dimethylamino) (hydroxy)methyl-9-methyl-1,10-phenanthroline] co pper(LI) and (aqua)dichloro(2,9-dimethyl-1,10-phenanroline)copper(II) quant itatively.