S. Kadir et A. Akbulut, Occurrence of sepiolite in the Hirsizdere sedimentary magnesite deposit, Bozkurt-Denizli, SW Turkey, CARBONAT EV, 16(1), 2001, pp. 17-25
The Hirsizdere magnesite deposit is found in the upper Miocene-Pliocene lac
ustrine sediments of the Cameli formation in the western Aegean depression
zone, which was uplifted to form a broad anticline and in which consecutive
faults and fractures developed due to the neotectonic activities. Thick al
ternation of carbonate cemented and weakly cemented conglomerate, sandstone
, mudstone intercalated with a few thin dolomite and magnesite layers is ex
posed at the lower part of the sequence. These units are overlain by magnes
ite and dolomite in association with thin claystone and sandstone layers an
d lenses. Green and claret red-brown smectite is observed in detrital mater
ials as well as in sandy carbonate units, and is accompanied by serpentine,
amphibole, illite, feldspar and quartz, whereas sepiolite is developed in
the form of 3-5 cm thick, yellow and greenish brown colored veins, or as th
in films lining parallel to the vein axis within the magnesite unit. SEM st
udies show that sepiolite fibers are grown in the form of meshworks and bri
dges between relict carbonate mineral grains. The presence of plant stem im
prints, and the abundance of gastropod and ostracode shells in carbonate un
its indicate shallow and alkaline lake conditions. Field observations and d
etailed mineralogical, chemical and micromorphological determinations indic
ate that sepiolite is formed by diagenetical transformation of magnesite du
ring the movement of silica-rich meteoric water through the fractures of ca
rbonate units under near-surface alkaline conditions.