The contribution made by triphenylphosphane in the putative catalysis by ruthenium species in conjugate additions of beta-dicarbonyl compounds

Authors
Lumbierres, M Marchi, C Moreno-Manas, M Sebastian, RM Vallribera, A Lago, E Molins, E
Citation
M. Lumbierres et al., The contribution made by triphenylphosphane in the putative catalysis by ruthenium species in conjugate additions of beta-dicarbonyl compounds, EUR J ORG C, (12), 2001, pp. 2321-2328
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
12
Year of publication
2001
Pages
2321 - 2328
Database
ISI
SICI code
1434-193X(200106):12<2321:TCMBTI>2.0.ZU;2-S
Abstract
Triphenylphosphane catalyzes conjugate additions of beta -dicarbonyl compou nds to pi -acceptor olefins and dialkyl azodicarboxylates. Formation of qua ternary centers at the nucleophiles has been achieved. The catalytic action of tris(triphenylphosphane)ruthenium(II) chloride and tetrakis(triphenylph osphane)ruthenium(II) hydride is at least partially due to the phosphane li gand.