Citation
A. Didier et al., A versatile and convenient method for the functionalization of porphyrins, EUR J ORG C, (10), 2001, pp. 1917-1926
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X
→ ACNP
Issue
10
Year of publication
2001
Pages
1917 - 1926
Database
ISI
SICI code
1434-193X(200105):10<1917:AVACMF>2.0.ZU;2-I
Abstract
The condensation of 3-(chloromethyl)benzoyl chloride with different atropis
omers of meso-(tetra-o-aminophenyl)porphyrin (TAPP), followed by the reacti
on of a series of nucleophilic reagents leads, among others, to precursors
of biomimetic models of heme proteins such as cytochrome c oxidase (CcO). T
his synthesis can also be applied as an efficient two-step reaction to obta
in highly functionalized porphyrin derivatives potentially useful for catio
n binding.