A unique growth mode of Ge on Si(110) substrates was clarified by phot
oluminescence (PL) spectroscopy. A spectral redshift and an increase o
f the relative no-phonon intensity were found for PL from the two-dime
nsional Ge layer on Si(110) compared to that on Si(100). These results
likely arise from nonuniformity in the Ge layer thickness owing to th
e step-bunched Si(110) surface and resultant exciton localization. The
two-dimensional to three-dimensional growth mode changeover was obser
ved as evidenced by emergence of broad PL from Ge islands. In contrast
to Ge on Si(100) PL from the wetting layer was found to show continuo
us redshift with increasing Ge coverage even after Ge island formation
. (C) 1997 American Institute of Physics.