A linear polymer manganese(III) complex; synthesis, crystal and molecular structure and magnetic properties of catena-mu-acetato-[N,N '-O-phenylenebis(salicylideneaminato)]-manganese(III)

Authors
Zhang, KL Xu, Y Zheng, CG Zhang, Y Wang, Z You, XZ
Citation
Kl. Zhang et al., A linear polymer manganese(III) complex; synthesis, crystal and molecular structure and magnetic properties of catena-mu-acetato-[N,N '-O-phenylenebis(salicylideneaminato)]-manganese(III), INORG CHIM, 318(1-2), 2001, pp. 61-66
Citations number
32
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
318
Issue
1-2
Year of publication
2001
Pages
61 - 66
Database
ISI
SICI code
0020-1693(20010618)318:1-2<61:ALPMCS>2.0.ZU;2-L
Abstract
The X-ray structural analyses reveal that the title complex contains the Mn (saloph) [saloph = N,N ' -O-phenylenebis(salicylide-neaminato)] moieties br idged by single acetato groups in an anti-anti configuration to form linear polymer chains. Variable temperature magnetic susceptibility measurements (4.7-270 K) show the occurrence of very weak antiferromagnetic interactions between the Mn(III) ions with J = -1.32 cm(-1) and D = -0.72 cm(-1). (C) 2 001 Elsevier Science B.V. All rights reserved.