The extraction of pure hydrogen from the fermentation of household waste by
a mixed anaerobic bacterial flora is demonstrated. Simulated household was
te (600 g) was fermented in a bioreactor, which was continuously sparged wi
th nitrogen (30 ml/min) fed in from the bottom. The gas stream from the bio
rector passes through a sulphide trap (ZnO) and then through a heated palla
dium-silver membrane reactor to separate hydrogen from the gas stream. In t
his way, waste remediation and biological hydrogen production is combined i
n a process where a large proportion of the hydrogen produced can be collec
ted, free of other gaseous species from the fermentation. (C) 2001 Internat
ional Association for Hydrogen Energy. Published by Elsevier Science Ltd. A
ll rights reserved.