The dielectric constants in mixed oxides ZrO2+Y2O3, Ta2O5+TiO2, Ta2O5+Y2O3,
and ZrO2+SiO2 are examined in the context of the oxide additivity rule for
molecular polarizability. The experimentally observed concentration depend
ence of the dielectric constant can be satisfactorily explained by taking a
ccount of effective molecular polarizability and molecular volume changes.
The simple rule thus enables predictive study of the dielectric constant of
oxide alloys. (C) 2001 American Institute of Physics.