SYNTHESIS AND REACTIVITIES OF A NOVEL FLAVOENZYME MODEL, 5-DEAZAFLAVIN WITH C-2-SYMMETRY

Authors
YANADA R YONEDA Y YAZAKI M MIMURA N TAGA T YONEDA F YANADA K
Citation
R. Yanada et al., SYNTHESIS AND REACTIVITIES OF A NOVEL FLAVOENZYME MODEL, 5-DEAZAFLAVIN WITH C-2-SYMMETRY, Tetrahedron : asymmetry, 8(14), 1997, pp. 2319-2323
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
8
Issue
14
Year of publication
1997
Pages
2319 - 2323
Database
ISI
SICI code
0957-4166(1997)8:14<2319:SAROAN>2.0.ZU;2-C
Abstract
The tide model compound represents a redox property of the active site of flavoenzymes and an environmental effect of the apoproteins. Its s tereostructure was elucidated by H-1-NMR spectra and energy minimum ca lculations. The stereoselectivity of this model was observed during th e reaction with Me2PNPH, as NAD(P)H model. (C) 1997 Elsevier Science L td.