Self-assembly of the symmetric diblock copolymer in a confined state: Monte Carlo simulation

Self-assembly of symmetric diblock copolymers in confined state has been in vestigated by means of Monte Carlo simulation method. The symmetric diblock copolymers were confined in two- (parallel walls or circle) or in three-di mensional (spherical pr cylindrical) space. There are interactions between these boundaries and the symmetric diblock polymers. These interactions and boundary shape resulted in the formation of novel self-assemble structures , e.g., strip, circle, core-multishell, and multibarrel-layer structures. S imulation results-predicated that it is possible to design different phase structures for block copolymers by adjusting boundary shape and boundary-bl ock copolymer interactions. (C) 2001 American Institute of Physics.