Citation
Ma. Zolfigol et al., One-pot nitration of phenols under mild and heterogeneous conditions, J CHEM R-S, (4), 2001, pp. 140-142
Citations number
55
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342
→ ACNP
Issue
4
Year of publication
2001
Pages
140 - 142
Database
ISI
SICI code
0308-2342(200104):4<140:ONOPUM>2.0.ZU;2-K
Abstract
Nitrophenols can be obtained via nitrosation-oxidation of phenols with Oxon
e (R), NaNO2 and wet SiO2 at room temperature in moderate to high yields. I
n situ generation of HNO2 and the radical cation mechanism via the nitrous
acid catalysed (NAC) pathway or hydrogen abstraction involving NO, appear t
o be applicable to phenol nitration using these reagents.