Ew. Wolff et al., FACTORS CONTROLLING THE ELECTRICAL-CONDUCTIVITY OF ICE FROM THE POLAR-REGIONS - A SUMMARY, JOURNAL OF PHYSICAL CHEMISTRY B, 101(32), 1997, pp. 6090-6094
Data on the relationship between the electrical conductivity and the c
hemistry of ice cores from the polar regions are summarized, The elect
rical conductivity measurement is used as a proxy for de conductivity,
while dielectric profiling gives high-frequency conductivity. The de
conductivity seems to be controlled entirely by the acidity of the ice
, with a secondary effect of the accompanying anion. There is no posit
ive response when huge excesses of sea salt, ammonium, or calcium are
present, except in ice where brine is present. The high-frequency cond
uctivity is controlled by acidity, ammonium, and chloride. This findin
g can be accommodated within Jaccard theory, but the relative response
at high frequency to the three ions seems puzzling. The possibility t
hat de conduction may be through grain boundaries can also not be disc
ounted.