METATHESIS OF SILICON-CONTAINING OLEFINS .14. RUTHENIUM-CATALYZED CROSS-METATHESIS OF TRISUBSTITUTED VINYLSILANES WITH LIGHT ALKENES

Authors
FOLTYNOWICZ Z MARCINIEC B
Citation
Z. Foltynowicz et B. Marciniec, METATHESIS OF SILICON-CONTAINING OLEFINS .14. RUTHENIUM-CATALYZED CROSS-METATHESIS OF TRISUBSTITUTED VINYLSILANES WITH LIGHT ALKENES, Applied organometallic chemistry, 11(8), 1997, pp. 667-671
Citations number
12
Categorie Soggetti
Chemistry Applied","Chemistry Inorganic & Nuclear
Journal title
Applied organometallic chemistry → ACNP
ISSN journal
02682605
Volume
11
Issue
8
Year of publication
1997
Pages
667 - 671
Database
ISI
SICI code
0268-2605(1997)11:8<667:MOSO.R>2.0.ZU;2-7
Abstract
In the cross-metathesis reaction of tri(methyl, ethoxy)vinylsilanes wi th propene and/or 1-butene catalyzed by RuCl2(PPh3)(3) activated in be nzene at 115-130 degrees C, a series of 1-alkenylsilanes of general fo rmula CH3(CH2)(m)CH = CHSiMe3-n(OEt)(n), where m = 0, 1, and n = 0-3 ( 1-silyl-1-alkenes), as well as of formula CH2 = C(Me)SiMe3-n(OEt)(n), where n = 1, 2 (2-silyl-1-alkenes), were obtained, Additional products determined were allysilanes of general formula CH2 = CHCH2SiMe3-n(OEt )(n) and CH3CH = CHCH2SiMe3-n(OEt)(n), where n = 1-3. (C) 1997 by John Wiley & Sons, Ltd.