The paper reports the results of characterization of four commercial surfac
e treatments on M2 tool steel substrates. The treatments characterized were
(a) TiN deposited by physical vapor deposition (PVD), (b) TiCN/TiN multila
yer also deposited by PVD, (c) diamond-like carbon (DLC) deposited by an io
n-assisted technique, and (d) vanadium carbide (VC) produced by a thermal d
iffusion process. The surface treatments were evaluated for characteristics
relevant to their tribological performance, such as thickness, roughness,
chemical composition, micro- and nanohardness, coating-substrate adhesion,
and wear resistance. In addition, a hardness model developed at the Univers
ity of Newcastle upon Tyne (United Kingdom) to correct for substrate effect
s was successfully applied. Nanohardness tests also yielded the elastic mod
ulus values of the surface treatments, while scratch testing used for deter
mining coating-substrate adhesion provided qualitative information on their
ductility.