Reevaluation in interpretation of hydrophobicity by scaled particle theory

Authors
Citation
M. Kodaka, Reevaluation in interpretation of hydrophobicity by scaled particle theory, J PHYS CH B, 105(24), 2001, pp. 5592-5594
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
105
Issue
24
Year of publication
2001
Pages
5592 - 5594
Database
ISI
SICI code
1520-6106(20010621)105:24<5592:RIIOHB>2.0.ZU;2-4
Abstract
Hydrophobicity is considered to be a phenomenon that nonpolar solutes have a poor solubility in water? which plays fundamental roles in many chemical and biological systems. On the basis of the scaled particle theory, it has been shown in the present study that hydrophobicity is not caused by the sm all size of water molecules but by their high packing density generated fro m strong molecular interaction, Solvophobicity, observed in some organic so lvents such as ethylene glycol, can be also explained consistently by the p resent method.