Characteristic length of the glass transition

Citation
E. Donth et al., Characteristic length of the glass transition, J PHYS-COND, 13(22), 2001, pp. L451-L462
Citations number
43
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS-CONDENSED MATTER
ISSN journal
09538984 → ACNP
Volume
13
Issue
22
Year of publication
2001
Pages
L451 - L462
Database
ISI
SICI code
0953-8984(20010604)13:22<L451:CLOTGT>2.0.ZU;2-L
Abstract
Three lengths for the dynamic glass transition will be compared: a kinemati c length from computer simulation, a heterogeneity length from multidimensi onal nuclear magnetic resonance, and a characteristic length from calorimet ry. A qualitatively consistent picture is obtained after discussion of thei r different origins. The difficulties with respect to measured and simulate d lengths ate exposed. Heat capacity spectroscopy data for temperatures and frequencies near and above the crossover region of the dynamic glass trans ition are reported for two substances: poIy(n-decyl methacrylate), PnDMA, a nd 6-(4-benzyl oxy phenyl)-1, 2, 3, 4 tetraphenyl fulvene, TPCP-BO.