STUDY OF THE POTENTIAL-TIME RESPONSE CORRESPONDING TO A CATALYTIC MECHANISM DURING THE FIRST CYCLE OF AN ALTERNATING-CURRENT

Authors
MOLINA A ALCARAZ ML LOPEZTENES M
Citation
A. Molina et al., STUDY OF THE POTENTIAL-TIME RESPONSE CORRESPONDING TO A CATALYTIC MECHANISM DURING THE FIRST CYCLE OF AN ALTERNATING-CURRENT, Anales de quimica, 93(3), 1997, pp. 153-160
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Anales de quimica → ACNP
ISSN journal
11302283
Volume
93
Issue
3
Year of publication
1997
Pages
153 - 160
Database
ISI
SICI code
1130-2283(1997)93:3<153:SOTPRC>2.0.ZU;2-G
Abstract
A theoretical study of the potential-time response corresponding to a catalytic mechanism when an alternating current is applied to a static mercury drop electrode is carried out. The experimental conditions un der which reduction or oxidation transition times can be reached are d iscussed. Methods for determining the equilibrium constant and the rat e constants of the chemical step are proposed.