In the formation of an Al-Al2O3 ceramic matrix composite by oxidizing an Al
-Si-Mg alloy it was found from electron microscopy that MgO appeared first
on the surface of the sample and followed bq the formation of MgAl2O4 spine
l. This order of appearance could be postulated by considering thr high par
tial pressure of Mg and the Gibbs free energy associated with each reaction
during annealing. The MgO inhibited thr oxidation of molten Al underneath
and preserved the Al metal inclusions, while spinel allowed oxygen to diffu
se into the Al alloy so that Al was oxidized to form the Al2O3 ceramic matr
ix. (C) 2001 Elsevier Science Ltd. All rights reserved.