The photoluminescence spectra of GaSe and Cd-doped GaSe single crystals wer
e investigated at 11 K. Sharp emission peaks due to excitons and phonons we
re observed in the single crystals. Broad emission peaks due to donor-accep
tor pair recombinations were also observed. Emission peaks due to the dopan
t Cd in the Cd-doped GaSe single crystal were observed.