Sw. Lee et al., Discharge capacitance of electric double layer capacitor with electrodes made of carbon nanotubes directly deposited on SUS304 plates, KOR J CHEM, 18(3), 2001, pp. 371-375
Carbon nanotubes were deposited directly on SUS304 plates by PECVD with ace
tylene and hydrogen as precursors under various deposition conditions. Rama
n spectroscopy showed that carbon nanotubes were not fully graphitized at t
he deposition temperatures, 600 to 750 degreesC, although defects decreased
with increase of deposition temperature. SEM microscopy showed that carbon
nanotubes were not straight, but their growth followed the tip growth mode
l. Pretreatment of the substrate such as polishing and dipping in I-IF solu
tion was required for the successful deposition. Using non-aqueous electrol
yte we fabricated electrical double layer capacitance (EDLC) with SUS304 pl
ates, on which carbon nanotubes were deposited, without any treatment, and
measured charge/discharge characteristics. Discharge capacitance decreased
with cycles from initial value of 128 F/g, but stabilized at 58 F/g after 5
0 cycles.