Secondary M,C precipitation was investigated in K40S cobalt-base alloy afte
r 100 h aging at 950 degreesC. The results showed that it was closely relat
ed to the tungsten-rich zones inherited from the as-cast condition and the
degeneration of the primary M7C3 carbide. A direct element reaction, 6M + C
--> M6C, in which C comes from the decomposition of the M7C3 carbides, is
suggested as the mechanism of secondary M6C precipitation in K40S alloy. (C
) 2001 Elsevier Science B.V. All rights reserved.