S. Hata et al., Short range order structures in fcc-based Ni-Mo studied by high resolutiontransmission electron microscopy with image processing, MAT SCI E A, 312(1-2), 2001, pp. 160-167
Modern high resolution transmission electron microscopy was employed in stu
dy of short range order (SRO) in fcc-based Ni-Mo, which is classified as '1
1/2 0 alloy'. Digital processing of high resolution transmission electron
microscope (HRTEM) images can give information about local atomic arrangeme
nts of SRO as well as their projection views. The HRTEM observation with im
age processing reveals the SRO structures in Ni-Mo depending upon the alloy
composition and the heat treatment. Subunit cell clusters of D1(a), D0(22)
and Pt2Mo structures are generated in the SRO states of Ni4Mo and Ni3Mo al
loys. In the initial SRO states, the number of Pt2Mo type clusters increase
s with Mo composition while that of D1(a) type decreases. The D1(a), D0(22)
and Pt2Mo type clusters increase in number in the early stages of subseque
nt ordering. The formation of D1(a), D0(22) and Pt2Mo type clusters in the
SRO states is rationalized in terms of the similar tendencies in atomic con
figuration between D1(a), D0(22) and Pt,Mo structures. (C) 2001 Elsevier Sc
ience B.V. All rights reserved.