Recent development in investigations of point defect structure in B2-type i
ntermetallics is surveyed, mainly focusing on those by authors' group. Syst
ematic X-ray and neutron diffraction experiments showed that B2 alloys exhi
bit hybrid defect behavior, i.e. four kinds of defects (antisite defects an
d vacancies) generally coexist in this type of materials. Careful density m
easurements strongly suggest that constitutional vacancies do not exist eve
n in NiAl. A thermodynamic model based on the Bragg-Williams method reprodu
ces well the observed trends in B2 NiAl and FeAl alloys. (C) 2001 Elsevier
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