Optical techniques can provide nondestructive, contactless determinations o
f foe-charge density in doped semiconductors. We discuss the use of photolu
minescence spectra to evaluate the free-charge density of doped semiconduct
or layers obtained by ion-beam implantation. A photoluminescence line-shape
model that includes the conduction band nonparabolicity, band-tailing and
band-gap narrowing effects is presented. The model is applied to Si+-implan
ted InP samples with electron densities in the 5 x 10(16)-5 x 10(18) cm(-3)
range. (C) 2001 Elsevier Science B.V. All rights reserved.