Phase transformations in implanted iron may strongly depend on the sample t
hickness. The effect essentially relies on lower impurity concentration req
uired for given phase formation in thin films when compared with thick laye
rs or bulk samples. The phase transformation in thin films is also more com
plete, a full transformation of thin Fe layers into iron nitrides was obser
ved, whereas in thick or bulk samples about 20% of Fe atoms remain in cryst
alline alpha -Fe phase. (C) 2001 Elsevier Science B.V. All rights reserved.