On the growth of overdoped Bi-2212 single crystals under high oxygen pressure

Overdoped Bi2Sr2CaCu2O8+delta (Bi-2212) Single crystals have been prepared by travelling solvent Boating zone technique under high oxygen pressure up to 10 bar. The effect of oxygen pressure on growth conditions is studied. I n contrast with air growth the instability of molten zone occurs under high oxygen pressure applied during the growth, in consequence of the precipita tion of impurity phases on crystallization front. The feed rods pre-melted over 4 bar oxygen pressure were found to contain minor impurity phases, and this could also affect the stability of molten zone. With increasing oxyge n pressure from 2 to 10 bar the ratio of Bi/Sr for the overdoped Bi-2212 cr ystals increases in subsequent to the decrease of c-axis from 30.890(6) to 30.653(8) Angstrom, while the T-c reduces from 95 to 81 K. Besides the oxyg en growth pressure T-c and DeltaT(c) of the overdoped crystals are influenc ed by growth rate and feed rod pre-melting conditions. (C) 2001 Published b y Elsevier Science B.V.